Dieses Dokument steht unter einer CreativeCommons Lizenz by/4.0
Verlagslink DOI: 10.1038/srep44139
Titel: Electrochemical tuning of the optical properties of nanoporous gold
Sprache: Englisch
Autor/Autorin: Jalas, Dirk
Shao, Li-Hua
Canchi, Rashmi
Okuma, Toshiya
Lang, Slawa
Petrov, Alexander
Weißmüller, Jörg
Eich, Manfred
Schlagwörter: Metamaterials;Nanophotonics and plasmonics
Erscheinungsdatum: 9-Mär-2017
Quellenangabe: Scientific Reports 7, Article number: 44139 (2017)
Zusammenfassung (englisch): Using optical in-situ measurements in an electrochemical environment, we study the electrochemical tuning of the transmission spectrum of films from the nanoporous gold (NPG) based optical metamaterial, including the effect of the ligament size. The long wavelength part of the transmission spectrum around 800 nm can be reversibly tuned via the applied electrode potential. The NPG behaves as diluted metal with its transition from dielectric to metallic response shifted to longer wavelengths. We find that the applied potential alters the charge carrier density to a comparable extent as in experiments on gold nanoparticles. However, compared to nanoparticles, a NPG optical metamaterial, due to its connected structure, shows a much stronger and more broadband change in optical transmission for the same change in charge carrier density. We were able to tune the transmission through an only 200 nm thin sample by 30%. In combination with an electrolyte the tunable NPG based optical metamaterial, which employs a very large surface-to-volume ratio is expected to play an important role in sensor applications, for photoelectrochemical water splitting into hydrogen and oxygen and for solar water purification.
URI: http://tubdok.tub.tuhh.de/handle/11420/1403
URN: urn:nbn:de:gbv:830-88216415
DOI: 10.15480/882.1400
ISSN: 2045-2322
Institut: Optische und Elektronische Materialien E-12
Werkstoffphysik und -technologie M-22
Dokumenttyp: (wissenschaftlicher) Artikel
Sponsor / Fördernde Einrichtung: DFG SFB 986 M3 projects C1 & B2; NSFC No. 51501011; Open Access Publishing Fonds TU Hamburg/DFG
Enthalten in den Sammlungen:tub.dok

Dateien zu dieser Ressource:
Datei Beschreibung GrößeFormat 
srep44139.pdfPublisher's Version1,05 MBAdobe PDFMiniaturbild
Öffnen/Anzeigen
srep44139-s1.pdfSupplementary Information322,4 kBAdobe PDFMiniaturbild
Öffnen/Anzeigen

Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons Creative Commons